Florida State University scientists have developed a mathematical model, explaining the growth, pattern formation, and self-healing properties of chemical gardens. These insights could lead to the development of self-repairing materials.
Since the mid-1600s, chemists have been fascinated with brightly colored, coral-like structures that form by mixing metal salts in a small bottle.
Until now, researchers have been unable to model how these deceptively simple tubular structures —called chemical gardens — work and the patterns and rules that govern their formation.
"In a materials context, it's very interesting," said FSU Professor of Chemistry and Biochemistry Oliver Steinbock. "They don't grow like crystals. A crystal has nice sharp corners and grows atom layer by atom layer. And when a hole occurs in a chemical garden, it's self-healing. These are really early steps in learning how to make materials that can reconfigure and repair themselves."
Typically, chemical gardens form when metal salt particles are put in a silicate solution. The dissolving salt reacts with the solution to create a semipermeable membrane that ejects upward in the solution, creating a biological-looking structure, similar to coral.
Scientists observed chemical gardens for the first time in 1646 and for years have been fascinated with their interesting formations. The chemistry is related to the formation of hydrothermal vents and the corrosion of steel surfaces where insoluble tubes can form.
"People realized these were peculiar things," Steinbock said. "They have a very long history in chemistry. It became more like a demonstration experiment, but in the past 10-20 years, scientists became interested in them again."
Inspiration for the mathematical model developed by Steinbock, along with postdoctoral researcher Bruno Batista and graduate student Amari Morris, came from experiments that steadily injected a salt solution into a larger volume of silicate solution between two horizontal plates. These showed distinct growth modes and that the material starts off as stretchy, but as it ages, the material becomes more rigid and tends to break.
The confinement between two layers allowed the researchers to simulate a number of different shape patterns, some looking like flowers, hair, spirals, and worms.
In their model, the researchers described how these patterns emerge over the course of the chemical garden's development. Salt solutions can vary a lot in chemical makeup, but their model explains the universality in formation.
For example, the patterns can consist of loose particles, folded membranes, or self-extending filaments. The model also validated observations that fresh membranes expand in response to microbreaches, demonstrating the material's self-healing capabilities.
"The good thing we got is we got into the essence of what is needed to describe the shape and growth of chemical gardens," Batista said.
Reference: "Pattern selection by material aging: Modeling chemical gardens in two and three dimensions" by Bruno C. Batista, Amari Z. Morris and Oliver Steinbock, 3 July 2023, Proceedings of the National Academy of Sciences.
DOI: 10.1073/pnas.2305172120
News
Scientists Unlock a New Way to Hear the Brain’s Hidden Language
Scientists can finally hear the brain’s quietest messages—unlocking the hidden code behind how neurons think, decide, and remember. Scientists have created a new protein that can capture the incoming chemical signals received by brain [...]
Does being infected or vaccinated first influence COVID-19 immunity?
A new study analyzing the immune response to COVID-19 in a Catalan cohort of health workers sheds light on an important question: does it matter whether a person was first infected or first vaccinated? [...]
We May Never Know if AI Is Conscious, Says Cambridge Philosopher
As claims about conscious AI grow louder, a Cambridge philosopher argues that we lack the evidence to know whether machines can truly be conscious, let alone morally significant. A philosopher at the University of [...]
AI Helped Scientists Stop a Virus With One Tiny Change
Using AI, researchers identified one tiny molecular interaction that viruses need to infect cells. Disrupting it stopped the virus before infection could begin. Washington State University scientists have uncovered a method to interfere with a key [...]
Deadly Hospital Fungus May Finally Have a Weakness
A deadly, drug-resistant hospital fungus may finally have a weakness—and scientists think they’ve found it. Researchers have identified a genetic process that could open the door to new treatments for a dangerous fungal infection [...]
Fever-Proof Bird Flu Variant Could Fuel the Next Pandemic
Bird flu viruses present a significant risk to humans because they can continue replicating at temperatures higher than a typical fever. Fever is one of the body’s main tools for slowing or stopping viral [...]
What could the future of nanoscience look like?
Society has a lot to thank for nanoscience. From improved health monitoring to reducing the size of electronics, scientists’ ability to delve deeper and better understand chemistry at the nanoscale has opened up numerous [...]
Scientists Melt Cancer’s Hidden “Power Hubs” and Stop Tumor Growth
Researchers discovered that in a rare kidney cancer, RNA builds droplet-like hubs that act as growth control centers inside tumor cells. By engineering a molecular switch to dissolve these hubs, they were able to halt cancer [...]
Platelet-inspired nanoparticles could improve treatment of inflammatory diseases
Scientists have developed platelet-inspired nanoparticles that deliver anti-inflammatory drugs directly to brain-computer interface implants, doubling their effectiveness. Scientists have found a way to improve the performance of brain-computer interface (BCI) electrodes by delivering anti-inflammatory drugs directly [...]
After 150 years, a new chapter in cancer therapy is finally beginning
For decades, researchers have been looking for ways to destroy cancer cells in a targeted manner without further weakening the body. But for many patients whose immune system is severely impaired by chemotherapy or radiation, [...]
Older chemical libraries show promise for fighting resistant strains of COVID-19 virus
SARS‑CoV‑2, the virus that causes COVID-19, continues to mutate, with some newer strains becoming less responsive to current antiviral treatments like Paxlovid. Now, University of California San Diego scientists and an international team of [...]
Lower doses of immunotherapy for skin cancer give better results, study suggests
According to a new study, lower doses of approved immunotherapy for malignant melanoma can give better results against tumors, while reducing side effects. This is reported by researchers at Karolinska Institutet in the Journal of the National [...]
Researchers highlight five pathways through which microplastics can harm the brain
Microplastics could be fueling neurodegenerative diseases like Alzheimer's and Parkinson's, with a new study highlighting five ways microplastics can trigger inflammation and damage in the brain. More than 57 million people live with dementia, [...]
Tiny Metal Nanodots Obliterate Cancer Cells While Largely Sparing Healthy Tissue
Scientists have developed tiny metal-oxide particles that push cancer cells past their stress limits while sparing healthy tissue. An international team led by RMIT University has developed tiny particles called nanodots, crafted from a metallic compound, [...]
Gold Nanoclusters Could Supercharge Quantum Computers
Researchers found that gold “super atoms” can behave like the atoms in top-tier quantum systems—only far easier to scale. These tiny clusters can be customized at the molecular level, offering a powerful, tunable foundation [...]
A single shot of HPV vaccine may be enough to fight cervical cancer, study finds
WASHINGTON -- A single HPV vaccination appears just as effective as two doses at preventing the viral infection that causes cervical cancer, researchers reported Wednesday. HPV, or human papillomavirus, is very common and spread [...]
